Filled clear pullulan capsules against a botanical ingredient.

Pullulan Capsules 101: The Essential Guide for Manufacturers

With their unique properties and advantages over more traditional options such as gelatin capsules, pullulan capsules are gaining popularity in the supplement manufacturing industry. These plant-based capsules have oxygen barrier protection, making them perfect for encapsulating sensitive active ingredients. They also originate from a completely natural source, increasing their appeal to the growing number of consumers who are becoming more conscious of what they put into their bodies. Pullulan capsules are also odorless, tasteless, and easy to digest and are rapidly becoming a preferred alternative to the synthetic HPMC capsules.1

This guide aims to help manufacturers understand the benefits, applications, and best practices for working with pullulan capsules, ensuring they make informed decisions when selecting capsule options best suited for their product formulations as well as their consumer base.

What Are Pullulan Capsules?

Pullulan is a polysaccharide polymer made from the starch of the fungus Aureobasidium pullulans. The reported first mention of its existence was in 1938, and in 1976 the Hayashibara Company began commercial production of pullulan.2 Because pullulan as a polymer is water-soluble, tasteless, and odorless with film-forming properties, it serves as an ideal material for manufacturing with capsules.

Key Properties of Pullulan Capsules:

  • Transparent and glossy finish
  • Strong oxygen barrier
  • Water-soluble and easy to digest
  • Comes from all-natural, plant-based sources

Common Use Cases

Pullulan capsules can be used to encapsulate ingredients that are sensitive to oxygen, such as probiotics.3 Due to their composition and origin, they are also commonly utilized in supplements that are certified as organic, vegan, and allergen-free. They also appeal to the growing demand for eco-friendly products because they are biodegradable and come from a sustainable source.

Benefits of Pullulan Capsules for Manufacturers

Manufacturers need capsules that protect ingredients, align with consumer needs, and work seamlessly with existing capsule filling equipment. Over other types of empty capsules, manufacturers often choose pullulan capsules for their functionality and consumer appeal.

A supplement bottle containing botanicals with green pullulan capsules spilling out.

Here’s why manufacturers prefer pullulan capsules:

1. Excellent Oxygen Barrier for Maximum Ingredient Protection

One of the most evident advantages of pullulan capsules is their exceptional oxygen barrier, which is significantly stronger than those of both HPMC capsules and gelatin capsules. This is important because many nutraceutical ingredients degrade when exposed to oxygen. Probiotics, botanicals, enzymes (such as Bromelain), and omega-3s (like Flaxseed Oil) can lose bioavailability if they are not properly protected. This is why the proper encapsulation is so vitally important. Pullulan capsules help prolong shelf life by blocking oxygen exposure, ensuring that active ingredients remain stable for longer.

2. Meeting the Plant-Based and Vegan Consumer Demand

The demand for vegan and plant-based supplements is still experiencing growth. The vegan supplement market’s valuation was estimated to be around USD 9.1 billion in 2024 and is projected to grow to USD 17.7 billion by 2034 at a CAGR of 6.9%.4 Consumers are desiring clean-label and non-GMO ethical alternatives to traditional animal-derived products like gelatin; for instance, more than 2 in 3 consumers globally believe they are somewhat influenced by a clean label.5

3. Optimized for High-Speed Capsule Manufacturing

Efficiency in capsule filling, storage, and packaging are important aspects to manufacturers. With their strong elasticity and durability, pullulan capsules are compatible with practically any type of high-speed capsule filling machine. Pullulan capsules possess strong film-forming properties that create a protective barrier.6 In the correct environmental conditions, pullulan capsules are less likely to become brittle and break during encapsulation in comparison to gelatin capsules.

4. Sustainability Aligns with Eco-Consumer Trends

The manufacturing of pullulan capsules results in a low environmental impact. Pullulan is produced through a fermentation process of a naturally occurring fungus, which makes it a sustainable option. Unlike gelatin, which is derived from animal collagen through intensive processing, pullulan is cultivated in controlled environments with minimal resource consumption. As a plant-based, organic material, pullulan capsules are also biodegradable.7

The following is a table that displays the features discussed above as well as a few additional ones:

Vivion Pullulan Capsule Benefits Chart. The chart is divided into three columns: 'Pullulan Capsule Features,' 'Benefits for Manufacturers,' and 'Why It Matters.' Features include Oxygen Barrier, Plant-Based & Vegan, Non-GMO & Allergen-Free, Strong Durability, Neutral Taste & Odor, and Eco-Friendly. Corresponding benefits include protecting sensitive ingredients, meeting clean-label demand, no risk of contamination, working in high-speed machines, no interference with flavors, and a lower carbon footprint. The 'Why It Matters' column highlights the impacts: Extends product shelf life, Expands market reach, Increases consumer trust, Reduces breakage & waste, Ideal for flavored supplements, and Aligns with green trends. The background features clear pullulan capsules, and the Vivion logo is displayed at the top.

Applications in Supplement Manufacturing

Pullulan capsules are a versatile option for supplement manufacturers, especially for formulas that require high oxygen protection, plant-based sourcing, and compatibility with sensitive ingredients. They work well with a wide range of nutraceuticals, herbal extracts, and specialty supplements.

Probiotics & Live Cultures

Probiotic supplements include living bacteria that require protection from air, moisture, and heat to remain efficacious in the human body. Because oxygen exposure can rapidly impact stability, pullulan’s oxygen barrier extends shelf life and maintains good bacterial viability throughout storage and transportation. Some studies have even indicated that pullulan also has prebiotic benefits.8

A petri dish containing probiotics next to filled clear capsules.

Why pullulan capsules are ideal for probiotics:

  • Protects against oxygen better than HPMC capsules and gelatin capsules.
  • Enhances stability in shelf-stored supplements.
  • Potentially enhances the viability of good bacteria.9

Herbal & Botanical Extracts

Many herbal and botanical extracts are extremely vulnerable to oxidation, moisture exposure, and deterioration over time. Pullulan capsules protect active ingredients, ensuring the bioavailability of herbal formulations.

Why pullulan capsules work for herbal supplements:

  • No interaction with sensitive plant-based ingredients.10
  • Meets organic supplement standards as it is naturally fermented.
  • Comprises a completely natural product when used with herbal & botanical extracts.

Sports Nutrition & Amino Acids

Sports supplements with amino acids have clean-label, high-quality delivery solutions that can satisfy the demands of health-conscious athletes. Pullulan capsules are a great option for fitness supplement manufacturers wanting to avoid synthetic materials and gelatin-based capsules.

Why pullulan is great for sports supplements:

  • Enhanced ingredient stability for performance-boosting ingredients like creatine.
  • Fast dissolution for quick absorption to ensure rapid delivery of nutrients.11
  • Moisture-resistant for hygroscopic ingredients like BCAAs and beta-alanine.12

Unique Use Cases for Specialty Formulations

For specialty formulations that require high stability, regulatory compliance, or plant-based sourcing, pullulan capsules are a good choice for manufacturers.

Examples of pullulan capsules’ uses in specialty supplements:

  • Sleep and relaxation supplements often include sensitive ingredients like valerian root, which can be protected by pullulan capsules.
  • Pullulan capsules can also protect nootropics such as lion’s mane and ginkgo biloba, making them ideal for cognitive support supplements.
  • Organic, Kosher, and Halal formulations have strict dietary standards, which pullulan capsules meet.

Manufacturing & Compatibility with Capsule Filling Machines

Encapsulation machines require capsule compatibility to ensure successful production, minimal waste, and high product quality. Pullulan capsules are intended to work with most common encapsulation equipment, however there are some best practices to follow for the best operational performance.

An image of a person, decked out in PPE, operating a high-speed capsule filling machine.

Optimizing Capsule Filling Machine Parameters for Pullulan Capsules

Pullulan capsules are compatible with most capsule filling machines; however, small adjustments to the machine may be needed to ensure optimal performance, especially for manufacturers transitioning from using a different type of capsule.

Key Production Factors for Pullulan Capsules:

  • Adjust Closing Force: Since pullulan capsules have a more elastic structure, excessive pressure may cause capsule deformation or cracking.
  • Minimize Static Build-Up: Static electricity can accumulate during machine operation, resulting in manufacturing problems. Use anti-static measures (such as ionizing air blowers) to reduce the chance of this happening.
  • Monitor Powder Flow Properties: If the encapsulated material is hygroscopic (e.g., inulin),13 establish proper powder consistency by using flow agents like silicon dioxide.

Preventing Pullulan Capsule Degradation with Proper Storage and Handling

Proper storage and handling is very important to maintaining the structural integrity of pullulan capsules. If they are not stored or handled correctly, there is a risk of capsule degradation happening.

Best Practices for Storing Pullulan Capsules:

  • Humidity Control: Maintain relative humidity at 35-60% to help prevent pullulan capsules from drying out or becoming sticky.14
  • Temperature Management: Store pullulan capsules in a cool, dry place at temperatures between 59-77°F.15
  • Sealed Packaging: Keep pullulan capsules in airtight containers to shield them from excessive moisture exposure.

What to Avoid When Storing Pullulan Capsules:

  • Excessive Heat: Heat can weaken capsule walls and cause deformation.
  • Direct Sunlight Exposure: Keep pullulan capsules out of direct sunlight. Exposure to direct sunlight may result in discoloration and breakdown of material.
  • High Humidity Conditions: High humidity can make capsules sticky, making capsules clump together or preventing capsules from rejoining/closing before their ejection.16

Filling Considerations of Powder Flow & Ingredient Compatibility

Pullulan capsules work well with a wide range of formulations, but manufacturers should be aware of certain filling properties that can assist with the smooth operation of the capsule filler.

Important Filling Considerations:

  • Fine Powder Flowability: Ingredients with poor flow qualities (e.g., sticky or static-prone powders) may require flow agents such as magnesium stearate to ensure seamless encapsulation.
  • Moisture Sensitivity: Hygroscopic ingredients (e.g., BCAAs and creatine) should be fully dried before filling to prevent clumping inside the filled capsule.

Regulatory Concerns & Certifications

Manufacturers must guarantee that their capsule materials meet global regulatory standards in order to remain compliant and promote their products effectively. Pullulan capsules have a considerable benefit in this regard because they are obtained from natural, fermentation-based sources, making them appropriate for several dietary and religious restrictions.

Compliance with Global Regulatory Standards

Pullulan capsules meet important international supplement and pharmaceutical standards, making them a reliable option for global distribution. They are safe for human consumption in the United States since they comply with FDA17 and USP (United States Pharmacopeia)18 requirements. In the European Union, they comply with EFSA (European Food Safety Authority)19 standards, allowing them to be used in dietary supplements sold throughout the continent. Pullulan capsules also meet the criteria of the Japanese Pharmacopeia (JP), ensuring its global recognition.20

Certifications Supporting Marketability

Pullulan capsules can be attractive to consumers since they can achieve various third-party certifications, making them more marketable for clean-label brands. Their plant-based origin qualifies them for vegan and vegetarian certifications, so they are a good fit for companies that cater to plant-based consumers.

Pullulan capsules are also Kosher and Halal approved, allowing supplement companies to offer products to religious dietary sectors. Many pullulan capsules are also non-GMO certified, which is becoming increasingly important to consumers looking for ingredient transparency in their supplements.

In the foreground, a hand holding a wooden spoon with filled clear capsules. In the background, various fruits and vegetables.

Meeting Consumer Expectations for Clean-Label Products

As consumers grow more careful of ingredients in their supplements, they often seek out products that meet organic, allergen-free, and sustainable standards. Pullulan capsules are free of animal derivatives, allergens, and synthetic materials, causing them to be a safer and more appealing choice for people with dietary restrictions.

Some pullulan capsules may qualify for organic certification because they are created using a fermentation technique rather than chemical alteration, depending on the supplier. This allows businesses to enter the growing organic supplement sector, which is driven by customer demand for clean, minimally processed products.

How to Choose the Right Pullulan Capsules for Your Manufacturing Needs

Before deciding on purchasing pullulan capsules, manufacturers need to consider factors such as capsule size, customization options, and supplier reliability. These factors play an important role in ensuring smooth operation, regulatory compliance, and strong market positioning for your encapsulated product.

Selecting the Right Capsule Size

Dosing accuracy, ingredient compatibility, and consumer experience directly influence the capsule size of your product. Pullulan capsules come in industry-standard sizes, with the most widely used being 00, 0, 1, and 2.

Larger capsules, such as size 00, are commonly used for high-dosage formulations like amino acids, herbal extracts, or multi-ingredient blends, while smaller capsules, such as size 2, are ideal for precise microdoses or powerful extracts.

Factors to Consider When Choosing Capsule Size:

  • Bulk Density of the Formulation: Light, fluffy powders work best with larger capsule sizes, while dense ingredients can fit into smaller capsules.
  • Consumer Swallowability: Smaller capsules may be easier to swallow for some consumer segments.
  • Filling Efficiency: The correct capsule size is required for accurate dosing and efficient machine operation with minimal waste.

Color & Customization for Branding and Differentiation

Custom capsules can be beneficial for brand identification, product distinction, and consumer loyalty. Pullulan capsules are available in transparent, opaque, and colored forms, allowing manufacturers to customize their capsules to meet specific branding and product requirements.

Transparent capsules are suitable for displaying high-quality materials like herbal powders or beadlet formulations, but opaque or colored capsules can shield sensitive substances from light while still adding visual appeal.21

Manufacturers can also custom print logos on pullulan capsules to make them more identifiable and memorable.

A close up of different capsules, some with two different colors, some clear with microbeadlets, some solid colors.

Sourcing from Reliable Suppliers

To ensure high quality, regulatory compliance, and successful manufacturing, choose a dependable pullulan capsule supplier. Because pullulan capsules are used to create ingestible products for the nutraceutical and pharmaceutical industries, procuring from a supplier who is committed to following strict quality assurance standards is of the utmost importance.

Evaluate pullulan capsule distributors based on the following:

  • Quality Assurance: Suppliers should provide COAs (Certificates of Analysis), certificates, tests, and other pertinent data at your request.
  • Regulatory Compliance: Ensure the supplier meets quality standards, such as responsible distribution verification or ISO 9001.
  • Capsule Stock Stability: Reliable sourcing provides consistent inventory availability, which reduces the risk of production delays.
  • Customization Capabilities: If prioritizing branding, choose a capsule supplier that provides color matching, printing, and other capsule customization options.

Pullulan capsules are a standout encapsulation solution for supplement manufacturers seeking a plant-based, high-performance, and clean-label alternative to standard gelatin capsules or HPMC capsules. Their excellent oxygen barrier, compatibility with sensitive ingredients, and ability to meet global regulatory standards make them a valid choice for a variety of applications, including probiotics, herbal extracts, sports nutrition, and functional supplements.

With pullulan capsules, manufacturers can guarantee product stability, appeal to health-conscious consumers, and increase their market reach into vegan/vegetarian, Kosher, Halal, and non-GMO products. If you’re looking to protect ingredients, establish branding with custom capsules, or address the rising demand for sustainable and plant-based supplements, pullulan capsules have the flexibility and dependability your production requires.


If you’re thinking of using pullulan capsules for your next product, why not test them first? Vivion offers free capsule samples to help you test them out with your formulation. Whether you need pullulan, gelatin, or HPMC capsules, our team can help you find the best option for your product line. Contact Vivion today to speak with the capsule experts.

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